Details
Reputable factory supply Ethyl trimethylacetate 3938-95-2 in stock with high standard
- Molecular Formula: C7H14O2
- Molecular Weight: 130.187
- Appearance/Colour: clear colorless liquid
- Vapor Pressure: 17mmHg at 25°C
- Melting Point: -90 °C
- Refractive Index: n20/D 1.391(lit.)
- Boiling Point: 118 °C at 760 mmHg
- Flash Point: 16.1 °C
- PSA: 26.30000
- Density: 0.881 g/cm3
- LogP: 1.59560
Ethyl trimethylacetate(Cas 3938-95-2) Usage
|
General Description |
Ethyl trimethylacetate undergoes condensation with acetophenone catalyzed by phosphazene base to yield β-trimethylsilyloxy ester. NCI(F?) and NCI(NH2?) mass spectra of a series of ethyl trimethylacetates have been studied. |
InChI:InChI=1/C7H14O2/c1-5-9-6(8)7(2,3)4/h5H2,1-4H3
3938-95-2 Relevant articles
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Lochmann,L.,Trekoval,J.
, p. 329 - 336 (1975)
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Exploring the catalytic activity of Lewis-acidic uranyl complexes in the nucleophilic acyl substitution of acid anhydrides
Takao, Koichiro,Akashi, Shin
, p. 12201 - 12207 (2017/03/08)
The catalytic activities of several uran...
Chemoselective CaO-mediated acylation of alcohols and amines in 2-methyltetrahydrofuran
Pace, Vittorio,Hoyos, Pilar,Alcántara, Andrés R.,Holzer, Wolfgang
, p. 905 - 910 (2013/07/27)
Calcium oxide is proposed as an innocuou...
Double molecular recognition with aminoorganoboron complexes: Selective alcoholysis of β-dicarbonyl derivatives
Oishi, Shunsuke,Saito, Susumu
supporting information; experimental part, p. 5395 - 5399 (2012/06/18)
Double duty: Aminoorganoboron (AOB) comp...
A mild and efficient chemoselective protection of primary alcohols as pivaloyl esters using La(NO3)3·6H2O as a catalyst under solvent-free conditions
Prabhakar,Suryakiran,Venkateswarlu
, p. 732 - 733 (2008/02/09)
Primary alcohols are selectively and eff...
3938-95-2 Process route
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-
64-17-5
ethanol
-
-
201230-82-2
carbon monoxide
-
-
75-65-0
tert -butyl alcohol
-
-
637-92-3
Ethyl tert-butyl ether
-
-
108-64-5
Ethyl isovalerate
-
-
3938-95-2
2,2-dimethyl-propanoic acid ethyl ester
-
-
115-11-7,15220-85-6
isobutene
| Conditions | Yield |
|---|---|
|
With
toluene-4-sulfonic acid;
bis-triphenylphosphine-palladium(II) chloride;
In
various solvent(s);
at 119.85 ℃;
for 12h;
under 45003.6 Torr;
Further Variations:;
Catalysts;
Solvents;
Temperatures;
Product distribution;
in ionic liquid;
|
-
-
64-17-5
ethanol
-
-
89549-37-1
N-pivaloyl benzamide
-
-
754-10-9
2,2-dimethylpropionamide
-
-
3938-95-2
2,2-dimethyl-propanoic acid ethyl ester
-
-
93-89-0,99341-95-4
benzoic acid ethyl ester
-
-
55-21-0,27208-38-4
benzamide
| Conditions | Yield |
|---|---|
|
With
C17H23BN2O;
at 25 ℃;
for 30h;
under 760.051 Torr;
chemoselective reaction;
Inert atmosphere;
|
3938-95-2 Upstream products
-
64-17-5
ethanol
-
859188-85-5
3-ethyl-5,5-dimethyl-hexane-2,4-dione
-
859772-12-6
3-butyl-5,5-dimethyl-hexane-2,4-dione
-
2648-71-7
3-bromo-3-methyl-2-butanone
3938-95-2 Downstream products
-
3970-62-5
2,2-dimethyl-3-pentanol
-
19549-70-3
2,2-dimethyl-heptan-3-ol
-
5340-80-7
5-tert-butyl-5-nonanol
-
71-36-3
butan-1-ol
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