Ethyl trimethylacetate

  • Name: Ethyl trimethylacetate
  • CAS: 3938-95-2
  • Purity: 99%
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Details

Reputable factory supply Ethyl trimethylacetate 3938-95-2 in stock with high standard

  • Molecular Formula: C7H14O2
  • Molecular Weight: 130.187
  • Appearance/Colour: clear colorless liquid 
  • Vapor Pressure: 17mmHg at 25°C 
  • Melting Point: -90 °C 
  • Refractive Index: n20/D 1.391(lit.)  
  • Boiling Point: 118 °C at 760 mmHg 
  • Flash Point: 16.1 °C 
  • PSA: 26.30000 
  • Density: 0.881 g/cm3 
  • LogP: 1.59560 

Ethyl trimethylacetate(Cas 3938-95-2) Usage

General Description

Ethyl trimethylacetate undergoes condensation with acetophenone catalyzed by phosphazene base to yield β-trimethylsilyloxy ester. NCI(F?) and NCI(NH2?) mass spectra of a series of ethyl trimethylacetates have been studied.

InChI:InChI=1/C7H14O2/c1-5-9-6(8)7(2,3)4/h5H2,1-4H3

3938-95-2 Relevant articles

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Lochmann,L.,Trekoval,J.

, p. 329 - 336 (1975)

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Exploring the catalytic activity of Lewis-acidic uranyl complexes in the nucleophilic acyl substitution of acid anhydrides

Takao, Koichiro,Akashi, Shin

, p. 12201 - 12207 (2017/03/08)

The catalytic activities of several uran...

Chemoselective CaO-mediated acylation of alcohols and amines in 2-methyltetrahydrofuran

Pace, Vittorio,Hoyos, Pilar,Alcántara, Andrés R.,Holzer, Wolfgang

, p. 905 - 910 (2013/07/27)

Calcium oxide is proposed as an innocuou...

Double molecular recognition with aminoorganoboron complexes: Selective alcoholysis of β-dicarbonyl derivatives

Oishi, Shunsuke,Saito, Susumu

supporting information; experimental part, p. 5395 - 5399 (2012/06/18)

Double duty: Aminoorganoboron (AOB) comp...

A mild and efficient chemoselective protection of primary alcohols as pivaloyl esters using La(NO3)3·6H2O as a catalyst under solvent-free conditions

Prabhakar,Suryakiran,Venkateswarlu

, p. 732 - 733 (2008/02/09)

Primary alcohols are selectively and eff...

3938-95-2 Process route

ethanol
64-17-5

ethanol

carbon monoxide
201230-82-2

carbon monoxide

<i>tert</i>-butyl alcohol
75-65-0

tert -butyl alcohol

Ethyl tert-butyl ether
637-92-3

Ethyl tert-butyl ether

Ethyl isovalerate
108-64-5

Ethyl isovalerate

2,2-dimethyl-propanoic acid ethyl ester
3938-95-2

2,2-dimethyl-propanoic acid ethyl ester

isobutene
115-11-7,15220-85-6

isobutene

Conditions
Conditions Yield
With toluene-4-sulfonic acid; bis-triphenylphosphine-palladium(II) chloride; In various solvent(s); at 119.85 ℃; for 12h; under 45003.6 Torr; Further Variations:; Catalysts; Solvents; Temperatures; Product distribution; in ionic liquid;
ethanol
64-17-5

ethanol

N-pivaloyl benzamide
89549-37-1

N-pivaloyl benzamide

2,2-dimethylpropionamide
754-10-9

2,2-dimethylpropionamide

2,2-dimethyl-propanoic acid ethyl ester
3938-95-2

2,2-dimethyl-propanoic acid ethyl ester

benzoic acid ethyl ester
93-89-0,99341-95-4

benzoic acid ethyl ester

benzamide
55-21-0,27208-38-4

benzamide

Conditions
Conditions Yield
With C17H23BN2O; at 25 ℃; for 30h; under 760.051 Torr; chemoselective reaction; Inert atmosphere;

3938-95-2 Upstream products

  • 64-17-5
    64-17-5

    ethanol

  • 859188-85-5
    859188-85-5

    3-ethyl-5,5-dimethyl-hexane-2,4-dione

  • 859772-12-6
    859772-12-6

    3-butyl-5,5-dimethyl-hexane-2,4-dione

  • 2648-71-7
    2648-71-7

    3-bromo-3-methyl-2-butanone

3938-95-2 Downstream products

  • 3970-62-5
    3970-62-5

    2,2-dimethyl-3-pentanol

  • 19549-70-3
    19549-70-3

    2,2-dimethyl-heptan-3-ol

  • 5340-80-7
    5340-80-7

    5-tert-butyl-5-nonanol

  • 71-36-3
    71-36-3

    butan-1-ol

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